Section 3: The Law of Definite Proportions

You are no doubt familiar with the chemical compound known as carbon dioxide.  From the time you were a child, you learned that we breath in oxygen and breath out carbon dioxide (a gross simplification of what actually happens, but nevertheless effective for teaching the respiratory system to a younger and probably cuter version of you).    You might even know that the chemical formula for carbon dioxide is CO2.  If not, you could probably deduce it from the name.

Carbon Dioxide, 1 carbon (shown in black), 2 oxygens (shown in red), always, no exceptions!

But has this compound always been known by this name? 

It has not.  Discovered in the middle 1700s, carbon dioxide was first known as “fixed air”.  It later became known as carbonic acid gas because when it was bubbled through water it made an acidic solution.  It didn’t get the name carbon dioxide until the combined observations of Joseph Proust, Joseph Priestley, and Antoine Lavoisier in 1794 led to what we now call the Law of Definite Proportions.

Combustion reactions like the one shown in this cozy campire produce carbon dioxide

The Law of Definite Proportions says that a given compound will have the same proportion of its constituent elements regardless of the size or location of the sample.  In other words, “fixed air” will consist of one carbon and two oxygen molecules whether it is the product of your breathing, or it comes from a campfire, or it is produced when a 4th grader mixes vinegar and baking soda in her volcano science fair project. 

This bubble is filled with carbon dioxide from my lungs, it floats on an invisible bed of carbon dioxide that has sublimated from the dry ice (also carbon dioxide) below it!
Because the elements of a given compound are always found in the same proportion, the mass percentage of those elements will also be the same for any given sample of a given compound.  For example, a sample of the sugar glucose will always contain 40% carbon, 6.7% hydrogen, and 53.3% oxygen by mass.  This is because each element has a specific mass and they are always found in the same proportion for a given substance.  For glucose, that would be 6 carbons to every 12 hydrogens, to every 6 oxygens, making the chemical formula for glucose, C6H12O6. Likewise, any given sample of water will contain 2 hydrogen atoms for every 1 oxygen atom.  Since hydrogen and oxygen atoms have unique and unchanging  masses, every water sample will contain 11.2% hydrogen and 88.8% oxygen by mass.  In other words, a 100 grams sample of water would be comprised of 11.2 grams of hydrogen and 88.8 grams of oxygen.